Abstract The physicochemical behavior of rubber may conveniently be described in terms of two main factors, (1) its long-chain character, and (2) its chemical nature. It is frequently possible to neglect one of these; e.g., Farmer and his coworkers have shown that much light can be thrown on the organic chemistry of rubber from a study of structurally related, low-molecular hydrocarbons. In the following we shall, in the main, consider rubber as a typical member of the class of long-chain compounds, and much of this section is therefore of general application to linear high polymers.
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