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"EFFICIENT HETEROGENEOUS SYNTHESIS OF POLYGALACTURONIC HYDROXAMIC ACID: A VERSATILE CHELATOR FOR METAL ION BINDING"

, HENDRYK WÜRFEL, , WENQIAN DANG, , THOMAS HEINZE · Cellulose Chemistry and Technology · 2023

"Polygalacturonic acid, the main structure of demethylated pectin, can be efficiently transformed with hydroxylamine to the corresponding hydroxamic acids in 2-propanol under heterogeneous conditions. The degree of transformation of the carboxylic acid function can be tailored and is significantly larger than when applying a homogeneous procedure. The polygalacturonic hydroxamic acids obtained show good water solubility and are capable of forming gels with Al3+, Fe3+ and Zn2+ ions. The amount of metal ions chelated by the hydroxamic acid derivative for Al3+ and Fe3+ is superior in comparison with the starting material."

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