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Sustainable Methods for Conversion of Cellulosic Biomass to Bio-Based Plastics: A Green Chemistry Approach

Mostafa M. Gaafar, Muhammad Hamza, Muhammad Husnain Manzoor, Islam Elsayed, El barbary Hassan · Sustainable Chemistry · 2026

Plastic manufacturing depends heavily on petroleum-derived monomers like terephthalic acid, the main component of polyethylene terephthalate (PET). However, the depletion of fossil resources and increasing environmental concerns have heightened the need for sustainable alternatives. Lignocellulosic biomass has emerged as a promising resource due to its renewable, abundant, and eco-friendly nature. Understanding its chemical composition enables conversion of this biomass into platform chemicals, such as 2,5-furandicarboxylic acid (FDCA) and lactic acid, derived from cellulose and hemicellulose. These can be polymerized into bio-based plastics such as polyethylene furanoate (PEF), polylactic acid (PLA), and polyhydroxyalkanoates (PHAs), offering greener alternatives to fossil-based plastics. PEF features rigid furan rings that enhance thermal stability, mechanical strength, and barrier properties, and reduce gas permeability compared to PET. PLA is a renewable, biodegradable plastic widely used in packaging and medical applications. This review covers the chemical composition of lignocellulosic biomass cellulose, hemicellulose, and lignin, and various pretreatment strategies, chemica

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