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Kinetic model of photoinitiated copolymerization of monofunctional monomers till high conversions

, Yuriy Medvedevskikh, Galyna Khovanets’, , Iryna Yevchuk, · Chemistry & Chemical Technology · 2009

Regularities of kinetics of photoinitiated copolymerization till high conversions in the systems of monofunctional methacrylate comonomers (hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA)) have been investigated by laser interferometry in a wide range of experimental factors (molar ratio of comonomers, photoinitiator concentration, intensity of UV-irradiation). Kinetic model of photoinitiated copolymerization of methacrylates till high conversions has been proposed on the basis of microheterogeneity conception of the polymerization process.

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