Probabilities or confidence values produced by artificial intelligence (AI) and machine learning (ML) models often do not reflect their true accuracy, with some models being under or overconfident in their predictions. For example, if a model is 80% sure of an outcome, is it correct 80% of the time? Probability calibration metrics measure the discrepancy between confidence and accuracy, providing an independent assessment of model calibration performance that complements traditional accuracy metrics. Understanding calibration is important when the outputs of multiple systems are combined, to avoid overconfident subsystems dominating the output. Such awareness also underpins assurance in safety or business-critical contexts and builds user trust in models. This article provides a comprehensive review of probability calibration metrics for classifier models, organizing them according to multiple groupings to highlight their relationships. We identify 94 metrics, and group them into four main families: point-based, bin-based, kernel or curve-based, and cumulative. For each metric, we catalog properties of interest and provide equations in a unified notation, facilitating implementatio
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