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Bis(diisobutylammonium) tetrachloridobis[3-(trifluoromethyl)phenyl]stannate

Xueqing Song, William Li · IUCrData · 2023

The asymmetric unit in the title salt, (C 8 H 20 N) 2 [SnCl 4 (C 7 H 4 Cl 2 F 3 ) 2 ], features a di- iso butylammonium cation in a general position and a diorganotin tetrachloride dianion, i.e . tetrachloridobis(3-trifuoromethylphenyl)stannate(IV), located on a centre of inversion; the Sn IV atom is octahedrally coordinated. In the crystal, charge-assisted N + —H...Cl hydrogen bonds along with C—H...F contacts occur within supramolecular layers that interdigitate along the a -axis direction.

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